Sun Jie's team from Tianjin University: Micro-multifunctional additives significantly improve the ultra-high voltage performance of 4.8 V nickel-rich cathode and silicon-oxygen anode batteries
Determined to win ‖ Sun Jie's team from Tianjin University: Micro-multifunctional additives significantly improve the ultra-high voltage performance of 4.8 V nickel-rich cathode and silicon-oxygen anode batteries
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Summary and Outlook
As a multifunctional electrolyte additive, FTDP significantly improves the electrochemical performance of the battery with nickel-rich cathode and silicon-oxygen anode by adding a trace amount of 0.2 wt.%. FTDP can preferentially decompose on the surface of the cathode and anode to participate in the formation of protective CEI and SEI . Specifically, the generated CEI rich in B and CN can effectively inhibit the dissolution of transition metal ions and maintain the integrity of the cathode, while the generated SEI rich in LiF and Li3N provides good mechanical properties and fast kinetics, thereby inhibiting the cracking of the anode and improving the high-rate performance. The multifunctionality of FTDP , including quenching free radicals, inhibiting the hydrolysis of LiPF6 and the generation of HF , further improves the stability of the electrode surface interface. Therefore, the NCM811 /Li battery exhibits excellent electrochemical performance even under harsh conditions such as ultra-high voltage (4.8 V) , high temperature ( 60 °C) and high rate ( 10 C) . In particular, the capacity retention rate is as high as 80.3 % after 200 cycles at an ultra-high voltage of 4.8 V and a current of 1 C. The excellent long-cycle performance of NCM811/SiO x soft-pack batteries also highlights the application potential of FTDP . This work provides a practical reference for the rational screening and design of single trace multifunctional electrolyte additives to promote the development of high-energy-density lithium-ion batteries .
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